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Neutralizing Acids and Bases

Quick Tips #148

Spills of hazardous substances must be absorbed, neutralized or controlled at the time of the incident in order to maintain workplace safety. Neutralization helps make spilled materials safer to handle and helps decrease the cost of disposal.

The best way to determine if a material is acidic or basic is to measure its pH. This can be accomplished with pH paper, chemical indicators or pH meters. The pH scale measures from 0 to 14. Chemicals with a pH of 0-3 are considered strong acids. Chemicals with a pH of 12-14 are considered strong bases. To be considered neutral, a chemical must have a pH of 7.

"Acid" comes from the Latin word "acidus," meaning sour. Acids typically will have a sour taste and a pH of less than 7. There are two types of acids: mineral (inorganic) acids such as sulfuric, hydrochloric or nitric and carboxylic (organic) acids such as formic or acetic. To neutralize acids, a weak base is used.

Bases have a bitter or astringent taste and a pH greater than 7. Bases are also called alkaline compounds and are neutralized by using a weak acid. Common bases are sodium hydroxide, potassium hydroxide and ammonia.

There are many different products available that aid in the neutralization of acids and bases. They can be as simple as a bag of citric acid or sodium bicarbonate, or as complex as a solidifier and a neutralizer combined. Some of the major considerations in selecting the best method of neutralization are safety (mixing chemicals is always a potentially dangerous process), cost (identifying the most economical neutralizing method) and convenience.

When neutralization occurs, the acid and base react, forming water, salt and heat. If the acid and base are both very strong (such as concentrated hydrochloric acid and concentrated sodium hydroxide), a violent reaction will occur. This is why most neutralizers are very weak—to help keep the reaction at a slow pace and lessen the evolution of heat and gas.

Most neutralizer manufacturers provide an estimated volume of acid/base that their product will neutralize. It can take a large amount of the product to neutralize an acid or base, especially if it is concentrated. Some neutralizers have a built-in color indicator to let you know when the spill is neutralized. Other neutralizers require you to check the pH with pH paper or a pH meter to monitor the neutralization process. Some neutralizers also solidify the spill as they neutralize, to help make the spill easier to pick up. See the comparison charts below for examples of treatment ratios for some common neutralizers.

Charts

Chart A

Gallons of Acid Neutralized
Acid Spill-X-A®
2.5 lbs.
Hazorb®
3.3 lbs.
Spilfyter® Dry Acid
2.0 lbs.
Acetic 99% .30 .40 .25
Hydrochloric 37% .27 .50 .31
Hydrofluoric 49% .25 * *
Nitric 70% .55 .40 *
Perchloric 70% .29 .53 *
Phosphoric 85% .30 .13 .10
Sulfuric 93% .30 .19 .27

 

Chart B

Gallons of Base Neutralized
Base Spill-X-C®
2.0 lbs.
Hazorb®
4.95 lbs.
Spilfyter® Dry Base
2.0 lbs.
Ammonium Hydroxide .41 .56 .25
Potassium Hydroxide .27 .42 .27
Sodium Hydroxide .17 .26 .18

* Not Applicable

Sources

ANSUL Spill X

Spilfyter

Xorb

(Rev. 9/2015)


Find even more information you can use to help make informed decisions about the regulatory issues you face in your workplace every day. View all Quick Tips Technical Resources at www.grainger.com/quicktips.

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Please Note:
The information contained in this publication is intended for general information purposes only and is based on information available as of the initial date of publication. No representation is made that the information or references are complete or remain current. This publication is not a substitute for review of the current applicable government regulations and standards specific to your location and business activity, and should not be construed as legal advice or opinion. Readers with specific questions should refer to the applicable standards or consult with an attorney.


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